In the next step, OER of [FeO4]2 and Ni2O3 under chemical conditions was investigated. Ali Akbari, M.S., Bagheri, R., Song, Z. et al. In order to further determine the thickness of -Ni(OH)2 nanoplates, AFM image is shown in Figure 2D and Supplementary Figure 1. Ni oxides are poor catalysts for OER, but the incorporation of Fe into Ni oxide forms an efficient catalyst for OER9,10,11,12. performed the experiments. A positive reduction potential indicates a spontaneous reaction. Provided by the Springer Nature SharedIt content-sharing initiative. C 111, 1492514931. PDF Ion Exchange for Dummies - Lenntech Image credit: Wikipedia Commons, public domain. The oxidation peaks shifted to higher potentials, and reduction peaks shifted to the lower potential in the presence of Fe ions. The effect of continuous addition of Fe salt (final concentrations in each step: 0.25, 0.50, 0.75 and 1.0mM) on the current density at 1.86V for the consecutive CVs (KOH, pH 13) of Ni foam (c). In Nioh 1 the focus is more on humanoid I feel while Nioh 2 focusey more on yokai. Wang, Q. (A) XRD patterns. Grosvenor, A. P., Biesinger, M. C., Smart, R. S. C. & McIntyre, N. S. New interpretations of XPS spectra of nickel metal and oxides. In addition, two oxygen bonds peaks can be observed from the O1s spectrum in Figure 2F. The key to writing proper ionic formulas is simple: the total positive charge must balance the total negative charge. In the presence of the Fe salt (0.25mM), the subtraction shows that the Fe salt decreases the capacitance of Ni oxide at 1.361.46V range (A area). At the end of the exchange process, the resin beads have loaded all cations and . Large-scale synthesis of coaxial carbon nanotube/Ni(OH)2 composites for asymmetric supercapacitor application. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate. CAS Trapping an iron (VI) water-splitting intermediate in nonaqueous media. The onset of OER is observed at 100mV lower by Fe-Ni oxide than Fe ions on graphite (Fig. The peak of Ni 2p3/2 is located at 855.6 eV with a shake-up satellite (denoted as Sat.) peak at about 861.5 eV; meanwhile, Ni 2p1/2 characteristic peak is located at 873.2 eV with a shake-up satellite peak at about 879.9 eV. Example 1. Characteristic Reactions of Nickel Ions (Ni) - Chemistry LibreTexts doi: 10.1039/C8TA06072J, Zhao, J., Li, Z., Yuan, X., Yang, Z., Zhang, M., Meng, A., et al. A trimetallic organometallic precursor for efficient water oxidation. An important property of the cell is missing from this list. A mini-review: emerging all-solid-state energy storage electrode materials for flexible devices. Catal. Najafpour, M. M. & Moghaddam, N. J. The asymmetric AFSC shows superior performance such as potential window (1.5 V), energy density (62 Wh kg1 at the power density of 1.5 kW kg1), cycling stability (about 82% capacitance remained over 5,000 cycles), and flexibility (about 86% capacitance remained over 1,500 folding times). Internet Explorer). A few important questions in this regard are: Whether OER of Ni2O3 is affected by the Fe(III) salt or not? 44, 973977, https://doi.org/10.1021/ie50509a022 (1952). Oxidation and Reduction - Division of Chemical Education, Purdue University ACS Appl. 5a), the consecutive CVs showed no clear increase in OER. This Fe-Ni oxide could be oxidized by K2FeO4 in the next state and can oxidize water in the next step. However, after a few consecutive CVs, the peak at 1.46V was observed, which shows a shift to the higher potential at 100th CV (1.48V) (Fig. 43, 33033323. 116, 28862936, https://doi.org/10.1021/acs.chemrev.5b00340 (2016). Article Formation of a Ni (OH)2 - ScienceDirect After 100 consecutive CVs at a scan rate of 25mV/s in the absence of adding Fe ions, the onset of OER and the peak are observed at 1.48 and 1.47Vby LSV, respectively (Fig. After adding the Fe salt at this range, a few increases (1.3 times) in OER was observed, which was constant during the time of reaction (Fig. Thus, relatively large amounts of Fe are on the surface of the electrode. 5). code: 01-076-2301; crystal system: Orthorhombic; a (): 3.8700; b (): 12.4000; c (): 3.0600; (): 90.0000; (): 90.0000; (): 90.0000; volume of cell: 586.38 3). The roles of dissolved Ni species in OER was reported by Hes group24. A 6, 1741717425. The practical application of AFSC devices. Chapter 4b,c), if we withdraw the Ni(II)/(III) oxidation/reduction peaks. Chem. Ni2O3 is relatively stable at alkaline conditions and in the presence of Fe(III). The b-values also indicate that the as-prepared -Ni(OH)2 nanoplates have excellent channels for ions intercalation. Ind. the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in To further understand the charge storage mechanism of as-prepared ultra-thin -Ni(OH)2 nanoplates, the capacity contribution category is discussed in detail. One limitation of water-splitting reaction is OER3. Figure 3F shows the cycling stability of -Ni(OH)2 electrode after charging-discharging 5,000 times at 3 A g1. 5d). Beverskog, B. and JavaScript. Ni(OH)2 nanoplates grown on graphene as advanced electrochemical pseudocapacitor materials. Schmidbaur, H. The history and the current revival of the oxo chemistry of iron in its highest oxidation states: FeVIFeVIII. 3a,b), which showed that a few Fe sites were enough to optimize OER by Ni oxide. The previous section described the spontaneous oxidation of copper by aqueous silver(I) ions, but no observed reaction with aqueous lead(II) ions. It is electroactive, being converted to the Ni(III) oxy-hydroxide, leading to widespread applications in rechargeable batteries. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/. In contrast to many Fe salts, [FeO4]2 is soluble under alkaline conditions. (2020). (2020). You are using a browser version with limited support for CSS. 4a, orange plot) of the CV in the absence of the Fe salt and the CV in the presence of the Fe salt is shown in Fig. 4.3: Formulas for Ionic Compounds - Chemistry LibreTexts Department of Chemistry, Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan, 45137-66731, Iran, Mohammad Saleh Ali Akbari&Mohammad Mahdi Najafpour, Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, 315201, China, Center of Climate Change and Global Warming, Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan, 45137-66731, Iran, Research Center for Basic Sciences & Modern Technologies (RBST), Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan, 45137-66731, Iran, You can also search for this author in (Supplementary Table 1; Ghosh et al., 2015; Salunkhe et al., 2015; Zhao et al., 2016; Wang et al., 2017; Liang et al., 2018; Liu et al., 2018; Qin et al., 2018; Yang et al., 2018; Zhang et al., 2018; Zhou et al., 2020). LSV of the Ni foam in KOH (pH13) showed that before adding [FeO4]2, the onset of OER is observed at 1.52V (in the paper, all potentials are reported vs. RHE) (Fig. Energy Environ. 29:1809004. doi: 10.1002/adfm.201809004, Huang, P., Lethien, C., Pinaud, S., Brousse, K., Laloo, R., Turq, V., et al. Inset of C is a high-magnification SEM image. [14], The Ni2+ ion is a known carcinogen. Wiechen, M., Najafpour, M., Allakhverdiev, S. I. The structure consists of Ni(OH)2 layers with intercalated anions or water. 8:1702787. doi: 10.1002/aenm.201702787, Zhao, Y., Hu, L.-F., Zhao, S.-Y., and Wu, L.-M. (2016). The research group found that the increased conductivity by Fe ions in Ni oxide structure is not enough to explain the increased activity in Ni oxide toward OER12. For (h,i), red and black indicate the Ni(II)/(III) oxidation peaks in the presence and absence of the Fe salt, respectively; green and blue indicate the Ni(III)/(II) reduction peaks in the presence and absence of the Fe salt, respectively. J. Phys. Formation of an insoluble compound will sometimes occur when a solution containing a particular cation (a positively charged ion) is mixed with another solution containing a particular anion (a negatively charged ion). These experiments show that: Ni2O3 is relatively stable at alkaline conditions. Chem. [7], The mineral form of Ni(OH)2, theophrastite, was first identified in the Vermion region of northern Greece, in 1980. 7). Sustainable Energy Fuels, 2021,5, 5236 Using adding Fe salt to Ni oxide/Ni interface needs no binder and related limitations for the binder. doi: 10.1039/c1cc13796d, Meng, C.-Z., Liu, C.-H., Chen, L.-Z., Hu, C.-H., and Fan, S.-S. (2010). B. 43, 42124216. It seems that the redox property of Ni(III) was used by Fe to increase in OER (B area in Fig. Rep. 9, 18, https://doi.org/10.1038/s41598-019-40236-y (2019). Energy Fuels 1, 658663, https://doi.org/10.1039/C7SE00064B (2017). Figure 6. Before adding the Fe salt at (0.141.86V) range (Fig. 2732 Density 9.91 g/cm 3 Characteristics: Nickel is a silvery-gray metal. After linear fitting log(i) and log(v), the curve shows in Figure 3D and the Adj. The 2nd CV is shown in blue. (2018). The salt slowly diffused toward the electrode, and an improvement in OER was observed. Figure 3 shows the electrochemical performance of as-prepared electrode based on ultra-thin -Ni(OH) 2 nanoplates [Ni(OH) 2 @Ni Foam] using the three-electrode system (vs. Hg/HgO). Blakemore, J. D., Crabtree, R. H. & Brudvig, G. W. Molecular catalysts for water oxidation. 4d, it is hypothesized that Ni(II)/(III) oxidation occurs before OER in pure Ni oxide and the absence of Fe. It can be seen that the thickness of -Ni(OH)2 nanoplate is about 2.4 0.2 nm, which is much thinner than those of -Ni(OH)2 in previous reports (Lu et al., 2011; Li et al., 2020). 4b. 32:2003684. doi: 10.1002/adma.202003684, Wang, H.-L., Casalongue, H.-S., Liang, Y.-Y., and Dai, H.-J. 17.3 Electrode and Cell Potentials - Chemistry 2e | OpenStax Article The small orange line indicates the effect of Fe impurity on the current density at 1.96V. KOH (pH13) was used for all experiments. Why Ni(II) hydroxide and not Ni 2 O 3 significantly induces the decomposition of K 2 FeO 4 could be related to the presence of labile Ni(II) ions on the surface of Ni(II) hydroxide, which contrary . A straight line can be observed in the range of low frequency, the slope of which represents the Warburg resistance (Rw), which is caused by the diffusing resistance of electrolyte ions transferring into the interior of ultra-thin -Ni(OH)2 nanoplates (Zhao et al., 2018). doi: 10.1039/D0DT00687D, Liang, M.-M., Zhao, M.-S., Wang, H.-Y., Shen, J.-F., and Song, X.-P. (2018). The mass loading of -Ni(OH)2 nanoplates (m) is about 1.6 mg cm2, which can be calculated by equation: m = m1 m0. ISSN 2045-2322 (online). From the magnified area of the high frequency portion, it can be determined that the RESR of the asymmetric AFSC is 0.5 (Inset of Figure 4E). The demonstrated performance for AFSCs suggests a great potential to convert and store energy for portable and wearable electronic devices. Fetching data from CrossRef. The effect of the step by step addition of Fe ions to Ni oxide was studied. 8c)31. (2014). 600(9), 17711779, https://doi.org/10.1016/j.susc.2006.01.041 (2006). Electrochim Acta 236, 1827. 5b). The study of Ni 2 O 3 H synthesis conditions outlined that -NiOOH and III-NiOOH phases display instability versus electrolyte at elevated temperature, leading to the irreversible formation of Ni 2 O 3 H . Positive ions move toward the positive electrode. The obvious potential plateaus correspond to the pseudocapacitive behavior during the energy conversion and storage. Chem. This may take some time to load. Impressively, at a power density of 1.5 kW kg1, the AFSC can keep a high energy density of 62 Wh kg1. Najafpour, M. M. et al. SEM images of the foam as an anode electrode after amperometry at 1.46V in KOH (pH13) in a two-compartment electrochemical cell for 2hours, showed nanoparticles (ca. open access Abstract Highly ordered, Ni (OH) Ni-nanowire-based receptor elements were electrochemically fabricated and tested for /NiOOH redox couple was performed in 0.5-mol L KOH using Keywords Amorphous Nickel hydroxides Ni nanowires Electro-catalytic oxidation Formaldehyde oxidation 1. Chemical reaction - Precipitation, Reactants, Products Pseudocapacitance: from fundamental understanding to high power energy storage materials. Structureactivity correlations in a nickelborate oxygen evolution catalyst. Mater. correct acknowledgement is given. The formula for an ionic compound must contain the same number of positive and negative charges so that the charges are balanced and it is neutral overall. It is possible to get 100 resistance for all elemental and therefore 100% elemental dmg nullify (as only fire, water and lightning attacks do elemental dmg) to reach complete elemental immunity. Why Ni(II) hydroxide and not Ni2O3 significantly induces the decomposition of K2FeO4 could be related to the presence of labile Ni(II) ions on the surface of Ni(II) hydroxide, which contrary to an inert Ni(III), quickly form an intermediate such as 1 shown in Fig. It is interesting that the green and orange plots are comparable (Fig. After adding the Fe salt at this range, a few increases (1.15 times) in OER was observed, which was constant during the time of reaction (Fig. However, it transforms to -Ni(OH)2 in alkaline solutions, leading to many investigations into the possibility of stabilized -Ni(OH)2 electrodes for industrial applications.
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